Can a stoichiometric mixture of oxygen and methane exist as a liquid at standard pressure and some (low) temperature?How to determine the vapor pressure of a glycerine and propylene glycol mixture?Given the volumes: determine the pH and the final temperature of a mixture knowing only the initial pH and the temperature of the un-mixed componentsCan a solid and liquid be miscible?What elements and/or substances without water are liquid at room temperature?Using vapor mole fraction and pressure to determine liquid mole fractionHow could I find the solubility of hydrocarbons such as iso- and n-Butane in liquid Methane?Interpretation of miscibility curvesIs vapour pressure of a liquid solution constant at a given temperature, no matter the size of closed container and amount of liquid taken?Properties of azeotropesIs there a stable and non-toxic hydro-nitrogen-oxygen compound that's liquid in room temperature?
Multi tool use
Creating two special characters
What is the difference between lands and mana?
How to explain what's wrong with this application of the chain rule?
It grows, but water kills it
What features enable the Su-25 Frogfoot to operate with such a wide variety of fuels?
A Trivial Diagnosis
awk assign to multiple variables at once
The Digit Triangles
A variation to the phrase "hanging over my shoulders"
Microchip documentation does not label CAN buss pins on micro controller pinout diagram
Is there a nicer/politer/more positive alternative for "negates"?
Short story about a deaf man, who cuts people tongues
How to draw a matrix with arrows in limited space
Will number of steps recorded on FitBit/any fitness tracker add up distance in PokemonGo?
Does an advisor owe his/her student anything? Will an advisor keep a PhD student only out of pity?
What is the English pronunciation of "pain au chocolat"?
Why do Radio Buttons not fill the entire outer circle?
Does Doodling or Improvising on the Piano Have Any Benefits?
What is the highest possible scrabble score for placing a single tile
Why is so much work done on numerical verification of the Riemann Hypothesis?
Is this part of the description of the Archfey warlock's Misty Escape feature redundant?
Why do some congregations only make noise at certain occasions of Haman?
How do I fix the group tension caused by my character stealing and possibly killing without provocation?
Does "he squandered his car on drink" sound natural?
Can a stoichiometric mixture of oxygen and methane exist as a liquid at standard pressure and some (low) temperature?
How to determine the vapor pressure of a glycerine and propylene glycol mixture?Given the volumes: determine the pH and the final temperature of a mixture knowing only the initial pH and the temperature of the un-mixed componentsCan a solid and liquid be miscible?What elements and/or substances without water are liquid at room temperature?Using vapor mole fraction and pressure to determine liquid mole fractionHow could I find the solubility of hydrocarbons such as iso- and n-Butane in liquid Methane?Interpretation of miscibility curvesIs vapour pressure of a liquid solution constant at a given temperature, no matter the size of closed container and amount of liquid taken?Properties of azeotropesIs there a stable and non-toxic hydro-nitrogen-oxygen compound that's liquid in room temperature?
$begingroup$
This answer to the question Pre-mixing cryogenic fuels and using only one fuel tank written by a non-chemist (me) begins with:
At STP:
- LOX's boiling point is 90.19 K
- Methane's freezing point is 90.7 K
This does not a priori prove that a solution of the two can not exist. However it does mean that they can not be handled as liquids at the same temperature, making mixing the two more difficult.
We know that liquid air exists which shows that LOX and LN2 can mix together. But methane is an organic molecules and we know that heavier $textC_n textH_2n+2$ hydrocarbons include oils and waxes don't like to dissolve in non-organic solvents.
A stoichiometric mixture of oxygen and methane would be 2:1 molar:
$$ce 2O2 + CH4 -> CO2 + 2H2O $$
Though the two can not be conveniently maintained as liquids at the same temperature, can a stoichiometric mixture of the two exist as a liquid at some (low) temperature and standard pressure?
solutions mixtures fuel liquids
asked 4 hours ago
uhohuhoh
1,646839
$endgroup$
add a comment |
$begingroup$
This answer to the question Pre-mixing cryogenic fuels and using only one fuel tank written by a non-chemist (me) begins with:
At STP:
- LOX's boiling point is 90.19 K
- Methane's freezing point is 90.7 K
This does not a priori prove that a solution of the two can not exist. However it does mean that they can not be handled as liquids at the same temperature, making mixing the two more difficult.
We know that liquid air exists which shows that LOX and LN2 can mix together. But methane is an organic molecules and we know that heavier $textC_n textH_2n+2$ hydrocarbons include oils and waxes don't like to dissolve in non-organic solvents.
A stoichiometric mixture of oxygen and methane would be 2:1 molar:
$$ce 2O2 + CH4 -> CO2 + 2H2O $$
Though the two can not be conveniently maintained as liquids at the same temperature, can a stoichiometric mixture of the two exist as a liquid at some (low) temperature and standard pressure?
solutions mixtures fuel liquids
asked 4 hours ago
uhohuhoh
1,646839
$endgroup$
1
$begingroup$
I am not sure if both thesolutionsandmixturestags apply here.
$endgroup$
– uhoh
4 hours ago
2
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
1
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
2
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago
add a comment |
$begingroup$
This answer to the question Pre-mixing cryogenic fuels and using only one fuel tank written by a non-chemist (me) begins with:
At STP:
- LOX's boiling point is 90.19 K
- Methane's freezing point is 90.7 K
This does not a priori prove that a solution of the two can not exist. However it does mean that they can not be handled as liquids at the same temperature, making mixing the two more difficult.
We know that liquid air exists which shows that LOX and LN2 can mix together. But methane is an organic molecules and we know that heavier $textC_n textH_2n+2$ hydrocarbons include oils and waxes don't like to dissolve in non-organic solvents.
A stoichiometric mixture of oxygen and methane would be 2:1 molar:
$$ce 2O2 + CH4 -> CO2 + 2H2O $$
Though the two can not be conveniently maintained as liquids at the same temperature, can a stoichiometric mixture of the two exist as a liquid at some (low) temperature and standard pressure?
solutions mixtures fuel liquids
asked 4 hours ago
uhohuhoh
1,646839
$endgroup$
This answer to the question Pre-mixing cryogenic fuels and using only one fuel tank written by a non-chemist (me) begins with:
At STP:
- LOX's boiling point is 90.19 K
- Methane's freezing point is 90.7 K
This does not a priori prove that a solution of the two can not exist. However it does mean that they can not be handled as liquids at the same temperature, making mixing the two more difficult.
We know that liquid air exists which shows that LOX and LN2 can mix together. But methane is an organic molecules and we know that heavier $textC_n textH_2n+2$ hydrocarbons include oils and waxes don't like to dissolve in non-organic solvents.
A stoichiometric mixture of oxygen and methane would be 2:1 molar:
$$ce 2O2 + CH4 -> CO2 + 2H2O $$
Though the two can not be conveniently maintained as liquids at the same temperature, can a stoichiometric mixture of the two exist as a liquid at some (low) temperature and standard pressure?
solutions mixtures fuel liquids
solutions mixtures fuel liquids
asked 4 hours ago
uhohuhoh
1,646839
asked 4 hours ago
uhohuhoh
1,646839
edited 4 hours ago
uhoh
asked 4 hours ago
uhohuhoh
1,646839
asked 4 hours ago
uhohuhoh
1,646839
asked 4 hours ago
uhohuhoh
1,646839
1,646839
1
$begingroup$
I am not sure if both thesolutionsandmixturestags apply here.
$endgroup$
– uhoh
4 hours ago
2
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
1
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
2
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago
add a comment |
1
$begingroup$
I am not sure if both thesolutionsandmixturestags apply here.
$endgroup$
– uhoh
4 hours ago
2
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
1
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
2
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago
1
1
$begingroup$
I am not sure if both the
solutions and mixtures tags apply here.$endgroup$
– uhoh
4 hours ago
$begingroup$
I am not sure if both the
solutions and mixtures tags apply here.$endgroup$
– uhoh
4 hours ago
2
2
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
1
1
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
2
2
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago
add a comment |
1 Answer
1
active
oldest
votes
$begingroup$
There's a NASA report that looks into this: "ON THE SOLUBILITIES AND RATES OF SOLUTION OF GASES IN LIQUID METHANE", Hibbard and Evans, 1968 and concludes that such mixtures are possible.
Starting on page 8:
Figure 5(a) presents the curves for oxygen, argon, carbon monoxide,
and nitrogen. Also shown are the two experimental values for nitrogen.
Agreement is excellent at 99.83K and good at 110.9K. The curves for
these gases show that solubility should decrease with increasing
temperature and the nitrogen data confirm this. This figure shows the
mole fraction solubility of oxygen to be 1.0 at 90K. This means that
oxygen, which has a normal boiling temperature of 90.1K would
continuously condense in, and be miscible in all proportions, with
liquid methane at 90K. This is confirmed by reference 11 where, in a
study of the solubility of methane in liquid oxygen, it was concluded
that these formed a near-ideal solution at -297 F (90K)
(emphasis added) Reference 11 mentioned in there is "Hydrocarbon-Oxygen Systems Solubility", McKinley and Wang, 1960 (unfortunately paywalled) which also has interesting discussion of the stability (i.e. presence or absence of a tendency to explode) of various mixtures.
Figure 5 is reproduced below. Note how the solubility of oxygen rises rapidly as temperature drops.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
add a comment |
Your Answer
StackExchange.ifUsing("editor", function ()
return StackExchange.using("mathjaxEditing", function ()
StackExchange.MarkdownEditor.creationCallbacks.add(function (editor, postfix)
StackExchange.mathjaxEditing.prepareWmdForMathJax(editor, postfix, [["$", "$"], ["\\(","\\)"]]);
);
);
, "mathjax-editing");
StackExchange.ready(function()
var channelOptions =
tags: "".split(" "),
id: "431"
;
initTagRenderer("".split(" "), "".split(" "), channelOptions);
StackExchange.using("externalEditor", function()
// Have to fire editor after snippets, if snippets enabled
if (StackExchange.settings.snippets.snippetsEnabled)
StackExchange.using("snippets", function()
createEditor();
);
else
createEditor();
);
function createEditor()
StackExchange.prepareEditor(
heartbeatType: 'answer',
autoActivateHeartbeat: false,
convertImagesToLinks: false,
noModals: true,
showLowRepImageUploadWarning: true,
reputationToPostImages: null,
bindNavPrevention: true,
postfix: "",
imageUploader:
brandingHtml: "Powered by u003ca class="icon-imgur-white" href="https://imgur.com/"u003eu003c/au003e",
contentPolicyHtml: "User contributions licensed under u003ca href="https://creativecommons.org/licenses/by-sa/3.0/"u003ecc by-sa 3.0 with attribution requiredu003c/au003e u003ca href="https://stackoverflow.com/legal/content-policy"u003e(content policy)u003c/au003e",
allowUrls: true
,
onDemand: true,
discardSelector: ".discard-answer"
,immediatelyShowMarkdownHelp:true
);
);
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
StackExchange.ready(
function ()
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f111355%2fcan-a-stoichiometric-mixture-of-oxygen-and-methane-exist-as-a-liquid-at-standard%23new-answer', 'question_page');
);
Post as a guest
Required, but never shown
1 Answer
1
active
oldest
votes
1 Answer
1
active
oldest
votes
active
oldest
votes
active
oldest
votes
$begingroup$
There's a NASA report that looks into this: "ON THE SOLUBILITIES AND RATES OF SOLUTION OF GASES IN LIQUID METHANE", Hibbard and Evans, 1968 and concludes that such mixtures are possible.
Starting on page 8:
Figure 5(a) presents the curves for oxygen, argon, carbon monoxide,
and nitrogen. Also shown are the two experimental values for nitrogen.
Agreement is excellent at 99.83K and good at 110.9K. The curves for
these gases show that solubility should decrease with increasing
temperature and the nitrogen data confirm this. This figure shows the
mole fraction solubility of oxygen to be 1.0 at 90K. This means that
oxygen, which has a normal boiling temperature of 90.1K would
continuously condense in, and be miscible in all proportions, with
liquid methane at 90K. This is confirmed by reference 11 where, in a
study of the solubility of methane in liquid oxygen, it was concluded
that these formed a near-ideal solution at -297 F (90K)
(emphasis added) Reference 11 mentioned in there is "Hydrocarbon-Oxygen Systems Solubility", McKinley and Wang, 1960 (unfortunately paywalled) which also has interesting discussion of the stability (i.e. presence or absence of a tendency to explode) of various mixtures.
Figure 5 is reproduced below. Note how the solubility of oxygen rises rapidly as temperature drops.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
add a comment |
$begingroup$
There's a NASA report that looks into this: "ON THE SOLUBILITIES AND RATES OF SOLUTION OF GASES IN LIQUID METHANE", Hibbard and Evans, 1968 and concludes that such mixtures are possible.
Starting on page 8:
Figure 5(a) presents the curves for oxygen, argon, carbon monoxide,
and nitrogen. Also shown are the two experimental values for nitrogen.
Agreement is excellent at 99.83K and good at 110.9K. The curves for
these gases show that solubility should decrease with increasing
temperature and the nitrogen data confirm this. This figure shows the
mole fraction solubility of oxygen to be 1.0 at 90K. This means that
oxygen, which has a normal boiling temperature of 90.1K would
continuously condense in, and be miscible in all proportions, with
liquid methane at 90K. This is confirmed by reference 11 where, in a
study of the solubility of methane in liquid oxygen, it was concluded
that these formed a near-ideal solution at -297 F (90K)
(emphasis added) Reference 11 mentioned in there is "Hydrocarbon-Oxygen Systems Solubility", McKinley and Wang, 1960 (unfortunately paywalled) which also has interesting discussion of the stability (i.e. presence or absence of a tendency to explode) of various mixtures.
Figure 5 is reproduced below. Note how the solubility of oxygen rises rapidly as temperature drops.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
add a comment |
$begingroup$
There's a NASA report that looks into this: "ON THE SOLUBILITIES AND RATES OF SOLUTION OF GASES IN LIQUID METHANE", Hibbard and Evans, 1968 and concludes that such mixtures are possible.
Starting on page 8:
Figure 5(a) presents the curves for oxygen, argon, carbon monoxide,
and nitrogen. Also shown are the two experimental values for nitrogen.
Agreement is excellent at 99.83K and good at 110.9K. The curves for
these gases show that solubility should decrease with increasing
temperature and the nitrogen data confirm this. This figure shows the
mole fraction solubility of oxygen to be 1.0 at 90K. This means that
oxygen, which has a normal boiling temperature of 90.1K would
continuously condense in, and be miscible in all proportions, with
liquid methane at 90K. This is confirmed by reference 11 where, in a
study of the solubility of methane in liquid oxygen, it was concluded
that these formed a near-ideal solution at -297 F (90K)
(emphasis added) Reference 11 mentioned in there is "Hydrocarbon-Oxygen Systems Solubility", McKinley and Wang, 1960 (unfortunately paywalled) which also has interesting discussion of the stability (i.e. presence or absence of a tendency to explode) of various mixtures.
Figure 5 is reproduced below. Note how the solubility of oxygen rises rapidly as temperature drops.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$endgroup$
There's a NASA report that looks into this: "ON THE SOLUBILITIES AND RATES OF SOLUTION OF GASES IN LIQUID METHANE", Hibbard and Evans, 1968 and concludes that such mixtures are possible.
Starting on page 8:
Figure 5(a) presents the curves for oxygen, argon, carbon monoxide,
and nitrogen. Also shown are the two experimental values for nitrogen.
Agreement is excellent at 99.83K and good at 110.9K. The curves for
these gases show that solubility should decrease with increasing
temperature and the nitrogen data confirm this. This figure shows the
mole fraction solubility of oxygen to be 1.0 at 90K. This means that
oxygen, which has a normal boiling temperature of 90.1K would
continuously condense in, and be miscible in all proportions, with
liquid methane at 90K. This is confirmed by reference 11 where, in a
study of the solubility of methane in liquid oxygen, it was concluded
that these formed a near-ideal solution at -297 F (90K)
(emphasis added) Reference 11 mentioned in there is "Hydrocarbon-Oxygen Systems Solubility", McKinley and Wang, 1960 (unfortunately paywalled) which also has interesting discussion of the stability (i.e. presence or absence of a tendency to explode) of various mixtures.
Figure 5 is reproduced below. Note how the solubility of oxygen rises rapidly as temperature drops.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
edited 18 mins ago
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
answered 48 mins ago
Bob JacobsenBob Jacobsen
1212
1212
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
New contributor
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
Bob Jacobsen is a new contributor to this site. Take care in asking for clarification, commenting, and answering.
Check out our Code of Conduct.
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
add a comment |
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
$begingroup$
Bingo! What a great find, thank you! I think you can (should) also post an answer at the linked question as well.
$endgroup$
– uhoh
39 mins ago
add a comment |
Thanks for contributing an answer to Chemistry Stack Exchange!
- Please be sure to answer the question. Provide details and share your research!
But avoid …
- Asking for help, clarification, or responding to other answers.
- Making statements based on opinion; back them up with references or personal experience.
Use MathJax to format equations. MathJax reference.
To learn more, see our tips on writing great answers.
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
StackExchange.ready(
function ()
StackExchange.openid.initPostLogin('.new-post-login', 'https%3a%2f%2fchemistry.stackexchange.com%2fquestions%2f111355%2fcan-a-stoichiometric-mixture-of-oxygen-and-methane-exist-as-a-liquid-at-standard%23new-answer', 'question_page');
);
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Sign up or log in
StackExchange.ready(function ()
StackExchange.helpers.onClickDraftSave('#login-link');
);
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Sign up using Google
Sign up using Facebook
Sign up using Email and Password
Post as a guest
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
Required, but never shown
XCt Mx40ci3jbAN5lygPgnFVzlNH4mKRGqGgO,sXZBmwr HcIRp,i6Yt,E6z28D12JzL146L8LZM8F
1
$begingroup$
I am not sure if both the
solutionsandmixturestags apply here.$endgroup$
– uhoh
4 hours ago
2
$begingroup$
With an appropriate heat of mixing, the solution might well be possible. Not sure if there is literature on this mixture, but if I have time I’ll give it a whirl...
$endgroup$
– Jon Custer
3 hours ago
1
$begingroup$
@JonCuster I hope "give it a whirl" doesn't mean you're going to try to mix the two!
$endgroup$
– uhoh
3 hours ago
2
$begingroup$
just trying to whip it into a nice froth for my coffee in the morning...
$endgroup$
– Jon Custer
3 hours ago